# Atomic Number Of K

Posted : admin On 15.08.2021

The maximum electrons that can be carried by the sub-shell S is 2, by P is 6, by D is 10, and the F sub-shell can carry 14. This decides the electron capacity of the shells. The K shell contains a 1s subshell hence it can carry 2 electrons, the L shell has 2s and 2p, and can carry 8 electrons. Atomic number is the number of Protons present in the nuclei of an element. It decides the position of the element in the periodic table Potassium (K) has 19 protons in its nuclei. Therefore, its atomic number is 19. Potassium-39 Please visit the Potassium element page for information specific to the chemical element of the periodic table. EEE460-Handout Dec. Holbert ATOMIC NUMBER DENSITY Number of Atoms (n) and Number Density (N) The number of atoms or molecules (n) in a mass (m) of a pure material having atomic or molecular weight (M) is easily computed from the following equation using Avogadro's number (NA = 6.022×1023 atoms or molecules per gram-mole).

An explanation of the superscripts and subscripts seen in atomic number notation. Atomic number is the number of protons, and therefore also the total positive charge, in the atomic nucleus.
The Rutherford–Bohr model of the hydrogen atom (Z = 1) or a hydrogen-like ion (Z > 1). In this model it is an essential feature that the photon energy (or frequency) of the electromagnetic radiation emitted (shown) when an electron jumps from one orbital to another be proportional to the mathematical square of atomic charge (Z2). Experimental measurement by Henry Moseley of this radiation for many elements (from Z = 13 to 92) showed the results as predicted by Bohr. Both the concept of atomic number and the Bohr model were thereby given scientific credence.

The atomic number or proton number (symbol Z) of a chemical element is the number of protons found in the nucleus of every atom of that element. The atomic number uniquely identifies a chemical element. It is identical to the charge number of the nucleus. In an uncharged atom, the atomic number is also equal to the number of electrons.

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The sum of the atomic number Z and the number of neutronsN gives the mass numberA of an atom. Since protons and neutrons have approximately the same mass (and the mass of the electrons is negligible for many purposes) and the mass defect of nucleon binding is always small compared to the nucleon mass, the atomic mass of any atom, when expressed in unified atomic mass units (making a quantity called the 'relative isotopic mass'), is within 1% of the whole number A.

Atoms with the same atomic number but different neutron numbers, and hence different mass numbers, are known as isotopes. A little more than three-quarters of naturally occurring elements exist as a mixture of isotopes (see monoisotopic elements), and the average isotopic mass of an isotopic mixture for an element (called the relative atomic mass) in a defined environment on Earth, determines the element's standard atomic weight. Historically, it was these atomic weights of elements (in comparison to hydrogen) that were the quantities measurable by chemists in the 19th century.

The conventional symbol Z comes from the German word Zahl meaning number, which, before the modern synthesis of ideas from chemistry and physics, merely denoted an element's numerical place in the periodic table, whose order is approximately, but not completely, consistent with the order of the elements by atomic weights. Only after 1915, with the suggestion and evidence that this Z number was also the nuclear charge and a physical characteristic of atoms, did the word Atomzahl (and its English equivalent atomic number) come into common use in this context.

## History

### The periodic table and a natural number for each element

Russian chemist Dmitri Mendeleev, creator of the periodic table.

Loosely speaking, the existence or construction of a periodic table of elements creates an ordering of the elements, and so they can be numbered in order.

Dmitri Mendeleev claimed that he arranged his first periodic tables (first published on March 6, 1869) in order of atomic weight ('Atomgewicht').[1] However, in consideration of the elements' observed chemical properties, he changed the order slightly and placed tellurium (atomic weight 127.6) ahead of iodine (atomic weight 126.9).[1][2] This placement is consistent with the modern practice of ordering the elements by proton number, Z, but that number was not known or suspected at the time.

Niels Bohr, creator of the Bohr model.

A simple numbering based on periodic table position was never entirely satisfactory, however. Besides the case of iodine and tellurium, later several other pairs of elements (such as argon and potassium, cobalt and nickel) were known to have nearly identical or reversed atomic weights, thus requiring their placement in the periodic table to be determined by their chemical properties. However the gradual identification of more and more chemically similar lanthanide elements, whose atomic number was not obvious, led to inconsistency and uncertainty in the periodic numbering of elements at least from lutetium (element 71) onward (hafnium was not known at this time).

### The Rutherford-Bohr model and van den Broek

In 1911, Ernest Rutherford gave a model of the atom in which a central nucleus held most of the atom's mass and a positive charge which, in units of the electron's charge, was to be approximately equal to half of the atom's atomic weight, expressed in numbers of hydrogen atoms. This central charge would thus be approximately half the atomic weight (though it was almost 25% different from the atomic number of gold (Z = 79, A = 197), the single element from which Rutherford made his guess). Nevertheless, in spite of Rutherford's estimation that gold had a central charge of about 100 (but was element Z = 79 on the periodic table), a month after Rutherford's paper appeared, Antonius van den Broek first formally suggested that the central charge and number of electrons in an atom was exactly equal to its place in the periodic table (also known as element number, atomic number, and symbolized Z). This proved eventually to be the case.

### Moseley's 1913 experiment

Henry Moseley in his lab.

The experimental position improved dramatically after research by Henry Moseley in 1913.[3] Moseley, after discussions with Bohr who was at the same lab (and who had used Van den Broek's hypothesis in his Bohr model of the atom), decided to test Van den Broek's and Bohr's hypothesis directly, by seeing if spectral lines emitted from excited atoms fitted the Bohr theory's postulation that the frequency of the spectral lines be proportional to the square of Z.

To do this, Moseley measured the wavelengths of the innermost photon transitions (K and L lines) produced by the elements from aluminum (Z = 13) to gold (Z = 79) used as a series of movable anodic targets inside an x-ray tube.[4] The square root of the frequency of these photons (x-rays) increased from one target to the next in an arithmetic progression. This led to the conclusion (Moseley's law) that the atomic number does closely correspond (with an offset of one unit for K-lines, in Moseley's work) to the calculated electric charge of the nucleus, i.e. the element number Z. Among other things, Moseley demonstrated that the lanthanide series (from lanthanum to lutetium inclusive) must have 15 members—no fewer and no more—which was far from obvious from known chemistry at that time.

### Missing elements

After Moseley's death in 1915, the atomic numbers of all known elements from hydrogen to uranium (Z = 92) were examined by his method. There were seven elements (with Z < 92) which were not found and therefore identified as still undiscovered, corresponding to atomic numbers 43, 61, 72, 75, 85, 87 and 91.[5] From 1918 to 1947, all seven of these missing elements were discovered.[6] By this time, the first four transuranium elements had also been discovered, so that the periodic table was complete with no gaps as far as curium (Z = 96).

### The proton and the idea of nuclear electrons

In 1915, the reason for nuclear charge being quantized in units of Z, which were now recognized to be the same as the element number, was not understood. An old idea called Prout's hypothesis had postulated that the elements were all made of residues (or 'protyles') of the lightest element hydrogen, which in the Bohr-Rutherford model had a single electron and a nuclear charge of one. However, as early as 1907, Rutherford and Thomas Royds had shown that alpha particles, which had a charge of +2, were the nuclei of helium atoms, which had a mass four times that of hydrogen, not two times. If Prout's hypothesis were true, something had to be neutralizing some of the charge of the hydrogen nuclei present in the nuclei of heavier atoms.

In 1917, Rutherford succeeded in generating hydrogen nuclei from a nuclear reaction between alpha particles and nitrogen gas,[7] and believed he had proven Prout's law. He called the new heavy nuclear particles protons in 1920 (alternate names being proutons and protyles). It had been immediately apparent from the work of Moseley that the nuclei of heavy atoms have more than twice as much mass as would be expected from their being made of hydrogen nuclei, and thus there was required a hypothesis for the neutralization of the extra protons presumed present in all heavy nuclei. A helium nucleus was presumed to be composed of four protons plus two 'nuclear electrons' (electrons bound inside the nucleus) to cancel two of the charges. At the other end of the periodic table, a nucleus of gold with a mass 197 times that of hydrogen was thought to contain 118 nuclear electrons in the nucleus to give it a residual charge of +79, consistent with its atomic number.

### The discovery of the neutron makes Z the proton number

All consideration of nuclear electrons ended with James Chadwick's discovery of the neutron in 1932. An atom of gold now was seen as containing 118 neutrons rather than 118 nuclear electrons, and its positive charge now was realized to come entirely from a content of 79 protons. After 1932, therefore, an element's atomic number Z was also realized to be identical to the proton number of its nuclei.

## The symbol of Z

The conventional symbol Z possibly comes from the German word Atomzahl (atomic number).[8] However, prior to 1915, the word Zahl (simply number) was used for an element's assigned number in the periodic table.

## Chemical properties

Each element has a specific set of chemical properties as a consequence of the number of electrons present in the neutral atom, which is Z (the atomic number). The configuration of these electrons follows from the principles of quantum mechanics. The number of electrons in each element's electron shells, particularly the outermost valence shell, is the primary factor in determining its chemical bonding behavior. Hence, it is the atomic number alone that determines the chemical properties of an element; and it is for this reason that an element can be defined as consisting of any mixture of atoms with a given atomic number.

## New elements

The quest for new elements is usually described using atomic numbers. As of 2021, all elements with atomic numbers 1 to 118 have been observed. Synthesis of new elements is accomplished by bombarding target atoms of heavy elements with ions, such that the sum of the atomic numbers of the target and ion elements equals the atomic number of the element being created. In general, the half-life of a nuclide becomes shorter as atomic number increases, though undiscovered nuclides with certain 'magic' numbers of protons and neutrons may have relatively longer half-lives and comprise an island of stability.

 Look up atomic number in Wiktionary, the free dictionary.

## References

1. ^ abThe Periodic Table of Elements, American Institute of Physics
2. ^The Development of the Periodic Table, Royal Society of Chemistry
3. ^Ordering the Elements in the Periodic Table, Royal Chemical Society
4. ^Moseley, H.G.J. (1913). 'XCIII.The high-frequency spectra of the elements'. Philosophical Magazine. Series 6. 26 (156): 1024. doi:10.1080/14786441308635052. Archived from the original on 22 January 2010.
5. ^Eric Scerri, A tale of seven elements, (Oxford University Press 2013) ISBN978-0-19-539131-2, p.47
6. ^Scerri chaps. 3–9 (one chapter per element)
7. ^Ernest Rutherford NZHistory.net.nz, New Zealand history online. Nzhistory.net.nz (19 October 1937). Retrieved on 2011-01-26.
8. ^Origin of symbol Z. frostburg.edu

### Which has the larger atomic radius: Cl- or K+?

#### Explanation:

Atomic size is linked to two important concepts

### Atomic Number Of Kr 5s1

• the energy level on which the outermost electrons reside
• the effective nuclear charge of the nucleus

The first concepts is useful when dealing with atoms that are located in different periods of the periodic table.

In this case, the higher in energy an atom's outermost electrons are, the further away from the nucleus they will be. This in turn implies a larger atomic radius.

In the case of a neutral potassium atom, you know that its electron configuration looks like this

$' K : ' 1 {s}^{2} 2 {s}^{2} 2 {p}^{6} 3 {s}^{2} 3 {p}^{6} \textcolor{red}{4} {s}^{1}$

Potassium has its outermost electron on the fourth energy level. When the potassium cation is formed, that outermost electron is lost, which means that the electron configuration of $' K {'}^{+}$ is

$' K {'}^{+} : ' 1 {s}^{2} 2 {s}^{2} 2 {p}^{6} \textcolor{red}{3} {s}^{2} \textcolor{red}{3} {p}^{6}$

Its outermost electrons are now located on the third energy level.

Now take a look at a neutral chlorine atom

$' C l : ' 1 {s}^{2} 2 {s}^{2} 2 {p}^{6} \textcolor{red}{3} {s}^{2} \textcolor{red}{3} {p}^{5}$

### Atomic Number Of Krypton

Its outermost electrons are alredy on the third energy level. When the chloride anion is formed, an electron is being added to that same energy level, so that you have

$' C l {'}^{-} : ' 1 {s}^{2} 2 {s}^{2} 2 {p}^{6} \textcolor{red}{3} {s}^{2} \textcolor{red}{3} {p}^{6}$

The two ions have the same electron configuration, which means that they are isoelectronic.

Now turn to the second concept, effective nuclear charge.

Both ions have their outermost electrons located on the same energy level, but they do not have the same ionic radius.

### Atomic Number Of Kmno4

That happens because the number of protons each species has in its nucleus varies.

More specifically, potassium, which has an atomic number equal to $19$, has $19$ protons in its nucleus. Chlorine, on the other hand, only has $17$.

This is important because in the case of the potassium atom, the outermost electrons will be attracted by the nucleus more.

In other words, $' K {'}^{+}$ has bigger effective nuclear charge than $' C l {'}^{-}$, which translates to a bigger net positive charge felt by the outermost electrons.

This will compress the energy levels a bit and make the ionic radius smaller for the potassium cation.

Therefore, the chloride anion will have the larger atomic radius.